how we discovered the origin of these rare and mysterious walls

The Great Sand Sea Desert stretches over an area of ​​72,000km² connecting Egypt and Libya. If you find yourself in a particular part of the desert in southeast Libya and southwest Egypt, you will see pieces of yellow glass scattered across the sandy landscape.

It was first described in a scientific paper in 1933 and is called Libyan desert glass. It is prized by mineral collectors for its beauty, relative rarity – and mystery. There is a piece of glass in a suit found in the tomb of the Egyptian pharaoh Tutankhamun. Natural glasses are found elsewhere in the world; Examples include moldavites from the Ries crater in Europe and tektites from the Ivory Coast. But none are as rich in silica as the glass of the Libyan desert, and they are not found in such large lumps and quantities.

The origin of glass has been a matter of debate among scientists for almost a century. Some suggested it could be from volcanoes on the moon. Others suggest that it is the result of lightning strikes (“fulgurites” – glass that forms from the fusion of sand and soil when struck by lightning). Other theories suggest that it is the result of sedimentary or hydrothermal processes; caused by a huge meteor explosion in the air; or that it came from a nearby meteorite crater.

Now, thanks to advanced microscopy technology, we believe we have the answer. Together with colleagues from universities and scientific centers in Germany, Egypt and Morocco, I identified the glass of the Libyan desert that came from the impact of a meteorite on the Earth’s surface.

Space collisions are a primary process in the solar system, as planets and their natural satellites accrete through the asteroids and planetary embryos (also known as planetesimals) colliding with each other. These influences also helped our planet come together.

Under the microscope

In 1996 scientists determined that the glass was close to 29 million years old. A later study suggested that the original material consisted of quartz grains, coated with mixed clay minerals and oxides of iron and titanium.

This latter result raised more questions, since the proposed age is older than the matching source material in the relevant area of ​​the Great Sand Sea desert. To put it simply: those original materials did not exist in that location 29 million years ago.

For our recent study, a co-author obtained two pieces of glass from a local who collected them in the Al Jaouf region of southeastern Libya.

We studied the samples with a state-of-the-art transmission electron microscopy (TEM) technique, which allows us to see tiny particles of material – 20,000 times smaller than the thickness of a sheet of paper. Using this super high magnification technique, we found small minerals in this glass: different types of zirconium oxide (ZrO₂).

Minerals are composed of chemical elements, the atoms of which form a regular three-dimensional package. Imagine placing eggs or soda bottles on the supermarket shelf: layers upon layers to ensure the most efficient storage. Likewise, atoms assemble into a crystal lattice that is unique to each mineral. Minerals with the same chemical composition but different atomic structure (different ways of packing atoms into the crystal lattice) are called polymorphs.

One polymorph of ZrO₂ we observed in Libyan desert glass is called cubic zirconia – the type seen in some jewelery as a synthetic substitute for diamond. This mineral can only form at a high temperature between 2,250°C and 2,700°C.

Another polymorph of ZrO₂ that we have observed is a very rare one called ortho-II or OII. It creates at a very high pressure – about 130,000 atmospheres, a pressure unit.

Such pressure and temperature conditions gave us proof of the meteorite impact origin of the glass. That is because such conditions can only be found in the Earth’s crust through the impact of a meteorite or an atomic bomb explosion.

More mysteries to solve

If our findings are correct (and we believe they are), the parent crater – where the meteorite hits the Earth’s surface – should be somewhere nearby. The nearest meteorite craters, named GP and Oasis, are 2km and 18km in diameter respectively, and far away from where the glass we tested was found. They are too long and too small to be considered the parent craters for massive amounts of impact glass, all concentrated in one spot.

The Great Sand Sea Desert.  Sylvester Adams

The Great Sand Sea Desert. Sylvester Adams

So, while we’ve solved part of the mystery, there are still more questions. Where is the crater of the parents? How big is it – and where is it? Could it be corroded, deformed or covered in sand? Further investigations will be required, probably in the form of remote sensing studies combined with geophysics.

This article is republished from The Conversation, a non-profit, independent news organization that brings you reliable facts and analysis to help you make sense of our complex world. The Conversation has a variety of free newsletters.

It was written by: Elizaveta Kovaleva, University of the Western Cape.

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Elizaveta Kovaleva receives funding from the Alexander von Humboldt Foundation.

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